MCAT® ExamChemical and Physical Foundations of Biological SystemsMedium

A student is asked to identify the strongest reducing agent among the following elements. Which element is the strongest reducing agent?

  1. AFluorine (F)
  2. BOxygen (O)
  3. CChlorine (Cl)
  4. DLithium (Li)
Show answer & explanation

Correct answer: D. Lithium (Li)

A reducing agent is a substance that readily donates electrons (is oxidized) to another substance. The stronger the reducing agent, the more easily it loses electrons. Reducing strength generally increases down a group and decreases across a period from left to right on the periodic table. Alkali metals (Group 1), like Lithium, are excellent reducing agents because they have a strong tendency to lose their single valence electron. Halogens (F, Cl) and Oxygen are strong oxidizing agents, meaning they readily gain electrons.

Why the other options are wrong

  • A. Fluorine is the strongest oxidizing agent, meaning it readily gains electrons, so it is a very poor reducing agent.
  • B. Oxygen is a strong oxidizing agent, meaning it readily gains electrons, so it is a poor reducing agent.
  • C. Chlorine is a strong oxidizing agent, though less so than fluorine, and is a poor reducing agent.

Reducing Agent Strength

A reducing agent is a chemical species that donates electrons to another species in a redox reaction. The strength of a reducing agent is inversely related to its ionization energy and directly related to its tendency to be oxidized.

  • Strong reducing agents readily lose electrons.
  • Alkali metals (Group 1) are strong reducing agents.
  • Reducing strength increases down a group.
  • Reducing strength decreases across a period (left to right).

Memory trick: Left & Down = Reducing; Right & Up = Oxidizing.

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